Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

I. Nakamura; H. Itagaki; Y. Yamamoto

Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

I. Nakamura, H. Itagaki, Y. Yamamoto

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction mainly proceeds through cleavage of a distal bond of methylenecyclopropanes.

Original language	English
Pages (from-to)	1684-1692
Number of pages	9
Journal	Khimiya Geterotsiklicheskikh Soedinenii
Issue number	12
Publication status	Published - 2001 Dec 1

Keywords

Azepane derivative
Hydroamination
Methylenecyclopropane
Nitrogen pronudeophile
Palladium catalyst

ASJC Scopus subject areas

Organic Chemistry

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title = "Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines",

abstract = "The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction mainly proceeds through cleavage of a distal bond of methylenecyclopropanes.",

keywords = "Azepane derivative, Hydroamination, Methylenecyclopropane, Nitrogen pronudeophile, Palladium catalyst",

author = "I. Nakamura and H. Itagaki and Y. Yamamoto",

year = "2001",

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language = "English",

pages = "1684--1692",

journal = "Khimiya Geterotsiklicheskikh Soedinenii",

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publisher = "Latvian Institute of Organic Synthesis",

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T1 - Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

AU - Nakamura, I.

AU - Itagaki, H.

AU - Yamamoto, Y.

PY - 2001/12/1

Y1 - 2001/12/1

N2 - The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction mainly proceeds through cleavage of a distal bond of methylenecyclopropanes.

AB - The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction mainly proceeds through cleavage of a distal bond of methylenecyclopropanes.

KW - Azepane derivative

KW - Hydroamination

KW - Methylenecyclopropane

KW - Nitrogen pronudeophile

KW - Palladium catalyst

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JO - Khimiya Geterotsiklicheskikh Soedinenii

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