Abstract
The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction proceeds mainly through cleavage of a distal bond of methylenecyclopropanes.
Original language | English |
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Pages (from-to) | 1532-1540 |
Number of pages | 9 |
Journal | Chemistry of Heterocyclic Compounds |
Volume | 37 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2001 Dec |
Keywords
- Azepane derivative
- Hydroamination
- Methylenecyclopropane
- Nitrogen pronucleophile
- Palladium catalyst
ASJC Scopus subject areas
- Organic Chemistry