Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

I. Nakamura; H. Itagaki; Y. Yamamoto

doi:10.1023/A:1014513411239

Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

I. Nakamura, H. Itagaki, Y. Yamamoto

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction proceeds mainly through cleavage of a distal bond of methylenecyclopropanes.

Original language	English
Pages (from-to)	1532-1540
Number of pages	9
Journal	Chemistry of Heterocyclic Compounds
Volume	37
Issue number	12
DOIs	https://doi.org/10.1023/A:1014513411239
Publication status	Published - 2001 Dec

Keywords

Azepane derivative
Hydroamination
Methylenecyclopropane
Nitrogen pronucleophile
Palladium catalyst

ASJC Scopus subject areas

Organic Chemistry

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10.1023/A:1014513411239

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title = "Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines",

abstract = "The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction proceeds mainly through cleavage of a distal bond of methylenecyclopropanes.",

keywords = "Azepane derivative, Hydroamination, Methylenecyclopropane, Nitrogen pronucleophile, Palladium catalyst",

author = "I. Nakamura and H. Itagaki and Y. Yamamoto",

year = "2001",

month = dec,

doi = "10.1023/A:1014513411239",

language = "English",

volume = "37",

pages = "1532--1540",

journal = "Chemistry of Heterocyclic Compounds",

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publisher = "Springer New York",

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TY - JOUR

T1 - Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

AU - Nakamura, I.

AU - Itagaki, H.

AU - Yamamoto, Y.

PY - 2001/12

Y1 - 2001/12

N2 - The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction proceeds mainly through cleavage of a distal bond of methylenecyclopropanes.

AB - The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction proceeds mainly through cleavage of a distal bond of methylenecyclopropanes.

KW - Azepane derivative

KW - Hydroamination

KW - Methylenecyclopropane

KW - Nitrogen pronucleophile

KW - Palladium catalyst

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DO - 10.1023/A:1014513411239

M3 - Article

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VL - 37

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JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 12

ER -

Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

Abstract

Keywords

ASJC Scopus subject areas

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