Palladium-catalyzed inter- and intramolecular hydroamination of methylenecyclopropanes with amines

I. Nakamura, H. Itagaki, Y. Yamamoto

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The inter- and intramolecular addition of nitrogen pronucleophiles to methylenecyclopropanes proceeds smoothly in the presence of palladium catalyst, giving the corresponding hydroamination products in good to excellent yields. The reaction mainly proceeds through cleavage of a distal bond of methylenecyclopropanes.

Original languageEnglish
Pages (from-to)1684-1692
Number of pages9
JournalKhimiya Geterotsiklicheskikh Soedinenii
Issue number12
Publication statusPublished - 2001 Dec 1

Keywords

  • Azepane derivative
  • Hydroamination
  • Methylenecyclopropane
  • Nitrogen pronudeophile
  • Palladium catalyst

ASJC Scopus subject areas

  • Organic Chemistry

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