Palladium-catalyzed carbonyaltion of lactone-derived enol phosphates: Stereoselective construction of functionalized cyclic ethers from lactones

Makoto Sasaki, Shugo Honda, Tetsuji Noguchi, Hiroyuki Takakura, Kazuo Tachibana

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

A strategy for the functionalization of lactones to afford cyclic ethers has been developed. The present synthesis involves palladium(0)-catalyzed carbonylation of lactone-derived enol phosphates and stereoselective hydroboration.

Original languageEnglish
Pages (from-to)838-840
Number of pages3
JournalSynlett
Issue number6
Publication statusPublished - 2000 Jul 10
Externally publishedYes

Keywords

  • Carbonylations
  • Cyclic ether
  • Enol phosphate
  • Lactones
  • Palladium

ASJC Scopus subject areas

  • Organic Chemistry

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