Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines

Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

Research output: Contribution to journalArticlepeer-review

70 Citations (Scopus)

Abstract

Figure presented Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.

Original languageEnglish
Pages (from-to)1383-1385
Number of pages3
JournalOrganic letters
Volume9
Issue number7
DOIs
Publication statusPublished - 2007 Mar 29
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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