Palladium-catalyzed [3+2] cycloaddition of alkylidenecyclopropanes with imines

Byoung Ho Oh; Itaru Nakamura; Shinichi Saito; Yoshinori Yamamoto

doi:10.1016/S0040-4039(01)01206-0

Palladium-catalyzed [3+2] cycloaddition of alkylidenecyclopropanes with imines

Byoung Ho Oh, Itaru Nakamura, Shinichi Saito, Yoshinori Yamamoto

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Alkylidenecyclopropanes react with N-tosylimines in toluene in the presence of a catalytic amount of Pd(PPh₃)₄ to afford the corresponding [3+2] cycloaddition products, pyrrolidine derivatives, in good to excellent yields.

Original language	English
Pages (from-to)	6203-6205
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	35
DOIs	https://doi.org/10.1016/S0040-4039(01)01206-0
Publication status	Published - 2001 Aug 27

Keywords

Alkylidenecyclopropane
Cycloaddition
Imine
Palladium catalysts
Pyrrolidine

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Palladium-catalyzed [3+2] cycloaddition of alkylidenecyclopropanes with imines",

abstract = "Alkylidenecyclopropanes react with N-tosylimines in toluene in the presence of a catalytic amount of Pd(PPh3)4 to afford the corresponding [3+2] cycloaddition products, pyrrolidine derivatives, in good to excellent yields.",

keywords = "Alkylidenecyclopropane, Cycloaddition, Imine, Palladium catalysts, Pyrrolidine",

author = "Oh, {Byoung Ho} and Itaru Nakamura and Shinichi Saito and Yoshinori Yamamoto",

year = "2001",

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language = "English",

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T1 - Palladium-catalyzed [3+2] cycloaddition of alkylidenecyclopropanes with imines

AU - Oh, Byoung Ho

AU - Nakamura, Itaru

AU - Saito, Shinichi

AU - Yamamoto, Yoshinori

PY - 2001/8/27

Y1 - 2001/8/27

N2 - Alkylidenecyclopropanes react with N-tosylimines in toluene in the presence of a catalytic amount of Pd(PPh3)4 to afford the corresponding [3+2] cycloaddition products, pyrrolidine derivatives, in good to excellent yields.

AB - Alkylidenecyclopropanes react with N-tosylimines in toluene in the presence of a catalytic amount of Pd(PPh3)4 to afford the corresponding [3+2] cycloaddition products, pyrrolidine derivatives, in good to excellent yields.

KW - Alkylidenecyclopropane

KW - Cycloaddition

KW - Imine

KW - Palladium catalysts

KW - Pyrrolidine

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DO - 10.1016/S0040-4039(01)01206-0

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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