Palladium and platinum η2-disilyne complexes bearing an isolable dialkyldisilyne as a ligand

Shintaro Ishida, Ryutaro Sugawara, Yoshifumi Misawa, Takeaki Iwamoto

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Not so alkyne like: A dialkyldisilyne (left, green) that can be isolated is synthesized and fully characterized. It coordinates to palladium and platinum in a η2-fashion giving complexes (red) with a trans-bent geometry, in contrast to η2-alkyne complexes. The complexes showed significant metallacycle character.

Original languageEnglish
Pages (from-to)12869-12873
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number49
DOIs
Publication statusPublished - 2013 Dec 2

Keywords

  • disilyne
  • metallacycle
  • palladium
  • platinum
  • silicon

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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