Palladium and platinum η2-disilyne complexes bearing an isolable dialkyldisilyne as a ligand

Shintaro Ishida; Ryutaro Sugawara; Yoshifumi Misawa; Takeaki Iwamoto

doi:10.1002/anie.201308517

Palladium and platinum η²-disilyne complexes bearing an isolable dialkyldisilyne as a ligand

Shintaro Ishida, Ryutaro Sugawara, Yoshifumi Misawa, Takeaki Iwamoto

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Not so alkyne like: A dialkyldisilyne (left, green) that can be isolated is synthesized and fully characterized. It coordinates to palladium and platinum in a η²-fashion giving complexes (red) with a trans-bent geometry, in contrast to η²-alkyne complexes. The complexes showed significant metallacycle character.

Original language	English
Pages (from-to)	12869-12873
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	49
DOIs	https://doi.org/10.1002/anie.201308517
Publication status	Published - 2013 Dec 2

Keywords

disilyne
metallacycle
palladium
platinum
silicon

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201308517

Cite this

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AU - Iwamoto, Takeaki

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KW - platinum

KW - silicon

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