P-coordinated group VI metal(0) pentacarbonyl complexes of multiple-bond organophosphorus compounds in the low coordination state

Masaaki Yoshifuji, Katsuhiro Shibayama, Takashi Hashida, Kozo Toyota, Takashi Niitsu, Ikumi Matsuda, Takahiro Sato, Naoki Inamoto

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23 Citations (Scopus)

Abstract

Group VI metal(0) carbonyl complexes of diphosphenes, phosphaethylenes, 1-phosphaallene, and 1,3-diphosphaallene with the phosphorus atom in the low coordination state were prepared, and the 31P chemical shifts of these complexes were found to correlate to one another: the structures in solution could be determined by taking into account the correlation and phosphorus-tungsten coupling constants in 31P NMR.

Original languageEnglish
Pages (from-to)C63-C67
JournalJournal of Organometallic Chemistry
Volume311
Issue number3
DOIs
Publication statusPublished - 1986 Sep 9
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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