Oxygen K-Edge Fine Structure of Tl1Ba2Can-1CunO2n+3 Studied by Electron Energy Loss Spectroscopy

Daisuke Shindo, Hiroshi Sato, Gerald L. Liedl, Darold Perry, Kenji Hiraga, Makoto Hirabayashi, Satoru Nakajima, Masae Kikuchi, Yasuhiko Syono, Kiichi Hojou, Takeshi Soga

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14 Citations (Scopus)

Abstract

The fine structures of the oxygen K-edge in the Tl1Ba2Can-1CunO2n+3 with single Tl-O layers were investigated by electron energy loss spectroscopy (EELS). The peak corresponding to the hole state near the Fermi energy was sensitive to the number of Cu-O layers and the direction of momentum excitation. It was shown that the hole content in Tl1Ba2Can-1CunO2n+3 decreases with the increase of n (n=2−4) and that most holes exist in the O 2px, y orbitals of 2-dimensional Cu-O planes.

Original languageEnglish
Pages (from-to)L955-L958
JournalJapanese journal of applied physics
Volume28
Issue number6A
DOIs
Publication statusPublished - 1989 Jun

Keywords

  • Electron energy loss spectroscopy
  • High-T
  • Hole concentration
  • Near-edge fine structure
  • Oxygen K-edge
  • Superconductor
  • Tl-Ba-Ca-Cu-O

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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    Shindo, D., Sato, H., Liedl, G. L., Perry, D., Hiraga, K., Hirabayashi, M., Nakajima, S., Kikuchi, M., Syono, Y., Hojou, K., & Soga, T. (1989). Oxygen K-Edge Fine Structure of Tl1Ba2Can-1CunO2n+3 Studied by Electron Energy Loss Spectroscopy. Japanese journal of applied physics, 28(6A), L955-L958. https://doi.org/10.1143/JJAP.28.L955