Oxide composite prepared from intermetallic and amorphous Zr67Fe30M3- (M=Au, Pt) alloys and their catalytic activity for CO oxidation

Yung Han Huang, Sea Fue Wang, Satoshi Kameoka, Kanji Miyamoto, An Pang Tsai

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1 Citation (Scopus)

Abstract

In this study, Zr67Fe30M3 (M=Au, Pt) intermetallic compounds and amorphous alloys were prepared and used as precursors for the synthesis of oxides. Oxidation treatment of the intermetallic compounds at 500 °C followed by X-ray diffraction (XRD) analysis indicated that zirconium and iron were oxidized to ZrO2 and Fe2O3, respectively. In the case of Zr67Fe30M3 amorphous alloys, cubic Zr6Fe3O was observed on the surface of the ribbons after heat treatment at 500 °C in vacuum. Addition of 3% of gold or platinum to the alloy resulted in an increase in the lattice constants of the Zr6Fe3O phase. Grounding the treated ribbons into powders followed by an oxidation treatment at 500 °C in air produced Fe2O3 and ZrO2 supports, where Au and Pt are dissolved in the oxides as confirmed by X-ray photoelectron spectroscopy (XPS). No matter precursors are intermetallics or amorphous phases, the resultant oxides are the same. Although Pt and Au dissolved in the oxides, catalytic activities for CO oxidation were significant improved.

Original languageEnglish
Pages (from-to)49-56
Number of pages8
JournalJournal of Physics and Chemistry of Solids
Volume100
DOIs
Publication statusPublished - 2017 Jan 1

Keywords

  • Amorphous alloy
  • Gold
  • Intermetallics
  • Platinum
  • Zirconium oxide

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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