Oxidative rearrangement of tertiary allylic alcohols employing oxoammonium salts

Masatoshi Shibuya, Masaki Tomizawa, Yoshiharu Iwabuchi

Research output: Contribution to journalArticlepeer-review

84 Citations (Scopus)

Abstract

(Chemical Equation Presented) Practical and highly efficient methods for oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated carbonyl compounds employing oxoammonium salts are described. The methods developed are applicable to acyclic substrates as well as medium membered ring substrates and macrocyclic substrates. The counteranion of the oxoammonium salt plays crucial roles on this oxidative rearrangement.

Original languageEnglish
Pages (from-to)4750-4752
Number of pages3
JournalJournal of Organic Chemistry
Volume73
Issue number12
DOIs
Publication statusPublished - 2008 Jun 20

ASJC Scopus subject areas

  • Organic Chemistry

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