Abstract
(Chemical Equation Presented) A practical and environmentally friendly method for oxidative rearrangement of five- and six-membered cyclic tertiary allylic alcohols to β-disubstituted α,β-unsaturated ketones by the IBX/DMSO reagent system is described. Several conventional protecting groups (e.g., Ac, MOM, and TBDPS) are compatible under the reaction conditions prescribed.
Original language | English |
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Pages (from-to) | 4303-4306 |
Number of pages | 4 |
Journal | Organic letters |
Volume | 6 |
Issue number | 23 |
DOIs | |
Publication status | Published - 2004 Nov 11 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry