Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Masaki Hayashi, Masatoshi Shibuya, Yoshiharu Iwabuchi

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO +BF 4 -) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

Original languageEnglish
Pages (from-to)154-157
Number of pages4
JournalOrganic letters
Volume14
Issue number1
DOIs
Publication statusPublished - 2012 Jan 6

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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