Oxidation states of GaAs surface and their effects on neutral beam etching during nanopillar fabrication

C. Thomas, Y. Tamura, M. E. Syazwan, A. Higo, S. Samukawa

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

We have investigated a new process for fabricating GaAs sub-20 nm nanopillars that uses a top-down combination of a bio-template and damage-free neutral beam etching. A two-dimensional array of nanoparticles composed of a protein shell embedded with a metal oxide core was formed on the top of a GaAs surface treated by neutral beam oxidation. Because of device requirements, three low-temperature oxygen techniques were investigated for removing the protein shell prior to the etching process: oxygen radical, oxygen neutral beam, and low-temperature oxygen annealing in vacuum (LT-OAV). X-ray photoelectron spectroscopy was used to monitor the effects of the different treatments on the GaAs surface. While the three processes could efficiently remove a protein shell, subsequent oxidation of the GaAs surface showed some differences in the oxide layer composition. Therefore, LT-OAV was selected considering its lower gallium oxide formation. A hydrogen radical process was then performed at temperatures lower than 400 °C to remove the oxide layer prior to etching. This process completely removed arsenide oxide and only residual gallium oxide was found on the surface afterwards. Etching was performed using a pure chlorine neutral beam of GaAs samples with metal oxide core etching masks. We found that control of the Ga-oxide amount on the surface is the key parameter for controlling the diameter and the density of nanopillars. Finally, high-aspect ratio nanopillars using stacked layers of GaAs and AlGaAs were obtained and showed no damage layer.

Original languageEnglish
Article number215203
JournalJournal of Physics D: Applied Physics
Volume47
Issue number21
DOIs
Publication statusPublished - 2014 May 30

Keywords

  • gallium arsenide
  • neutral beam etching
  • oxide
  • quantum dots

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Acoustics and Ultrasonics
  • Surfaces, Coatings and Films

Fingerprint Dive into the research topics of 'Oxidation states of GaAs surface and their effects on neutral beam etching during nanopillar fabrication'. Together they form a unique fingerprint.

Cite this