Origin of unusual spinel-to-layered phase transformation by crystal water

Eunjeong Yang, Heejin Kim, Sangryun Kim, In Kim, Jaehoon Kim, Hyunjun Ji, Jang Wook Choi, Yousung Jung

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

It is well known that many layered transition metal oxides can transform into a spinel structure upon repeated battery cycling, but a phase transition in the opposite direction is rare. Recently, the transformation from spinel Mn3O4 to layered MnO2 was observed during the operation of a Mg battery in aqueous conditions, resulting in high performance Mg batteries. We hereby use ab initio calculations to unveil the mechanism by which crystal water plays a critical role in this unique transformation. Once inserted into the spinel form, a water molecule donates an electron, offering a key structural and thermodynamic driving force to initiate the transformation process. These crystal water molecules then get favorably clustered into a planar form in the layered structure and act as a stabilizing agent for birnessite. Kinetically, the inserted crystal water dramatically promotes the necessary rearrangement of Mn during the transition by lowering the activation barrier by >2 eV. The present structural, thermodynamic and kinetic understanding of the crystal water-driven phase transition provides novel insights to further the design of related low dimensional hydrated materials for multi-valent cathodes.

Original languageEnglish
Pages (from-to)433-438
Number of pages6
JournalChemical Science
Volume9
Issue number2
DOIs
Publication statusPublished - 2018

ASJC Scopus subject areas

  • Chemistry(all)

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