Origin and properties of second-order optical non-linearity in ultraviolet-poled GeO2-SiO2 glass

Takumi Fujiwara, Syuji Matsumoto, Motoshi Ohama, Akira J. Ikushima

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Progress in establishing larger second-order optical non-linearity in Ge-doped silica glass (15.7 GeO2-84.3 SiO2 in mol%) induced by simultaneous applications of a direct current (DC) electric field (≤ 105 V/cm) and ultraviolet laser irradiation (193 nm), the so-called the ultraviolet (UV)-poling method, is reported. The non-linearity thus induced has been shown to be affected by the GeE' centers created from oxygen deficient vacancies through photo-chemical reactions. In addition, we have found for the first time, to our knowledge, that crystallization in the glass is induced by the UV-poling, which leads to increase of third-order non-linearity, χ(3), approximately 15 times larger than that before UV-poling. Based on these results we suggest that origin of the second-order non-linearity in the glass induced by UV-poling is a combined effect of the third-order non-linearity possessed by the crystallites and an internal space-charge field where the charges are assumed to be produced during the formation of GeE′ centers.

Original languageEnglish
Pages (from-to)203-208
Number of pages6
JournalJournal of Non-Crystalline Solids
Volume273
Issue number1-3
DOIs
Publication statusPublished - 2000 Aug
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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