Organosiloxane transparent aerogels and hierarchically porous monoliths

Yasunori Kodera, Gen Hayase, Kazuyoshi Kanamori, Kazuki Nakanishi, Teiichi Hanada

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A transition of porous structures in monolithic poly(methylsilsesquioxane) (PMSQ, CH 3SiO 1.5) gels from uniform mesopores to hierarchical pore structures consisting of macro- and mesopores, has been investigated using a sol-gel system containing surfactant Pluronic F127. A broad variation of porous morphology is controlled by changing the concentration of F127. Sufficient concentrations of F127 inhibit the occurrence of macroscopic phase separation of hydrophobic PMSQ condensates and lead to well-defined mesoporous transparent aerogels with high specific pore volume. Mesopores are developed through microscopic phase separation of PMSQ colloid-surfactant complexes in the solvent. Macroscopic phase separation regulates well-defined macropores in the micrometer range on decreasing concentrations of F127, in which microscopic phase separation concurrently takes place in the PMSQ-rich gelling phase after the onset of macroscopic phase separation. Monolithic PMSQ gels with hierarchical macro- and mesopore structures are consequently obtained.

Original languageEnglish
Title of host publicationAerogels and Aerogel-Inspired Materials
Pages54-59
Number of pages6
DOIs
Publication statusPublished - 2011
Externally publishedYes
Event2010 MRS Fall Meeting - Boston, MA, United States
Duration: 2010 Nov 292010 Dec 3

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1306
ISSN (Print)0272-9172

Other

Other2010 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period10/11/2910/12/3

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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