Organocatalytic deprotonative functionalization of C(sp2)–H and C(sp3)–H bonds using in situ generated onium amide bases

Kiyofumi Inamoto, Hitomi Okawa, Hiroshi Taneda, Maomi Sato, Yutaro Hirono, Misato Yonemoto, Shoko Kikkawa, Yoshinori Kondo

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

Onium amides, generated in situ from the combination of aminosilanes and onium fluorides (R4PF, R4NF), are employed for the first time as bases for catalytic deprotonative functionalization of C(sp2)–H and activated C(sp3)–H bonds under mild conditions.

Original languageEnglish
Pages (from-to)9771-9773
Number of pages3
JournalChemical Communications
Volume48
Issue number78
DOIs
Publication statusPublished - 2012 Sep 5

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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