Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage

Daisuke Uraguchi, Keiichi Sorimachi, Masahiro Terada

Research output: Contribution to journalArticlepeer-review

177 Citations (Scopus)

Abstract

A new variant of phosphoric acid-catalyzed C-C bond forming reaction, direct alkylation of α-diazoester, via C-H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.

Original languageEnglish
Pages (from-to)9360-9361
Number of pages2
JournalJournal of the American Chemical Society
Volume127
Issue number26
DOIs
Publication statusPublished - 2005 Jul 6

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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