Organic Radical-Based Single-Molecule and Single-Chain Magnets

Keiichi Katoh, Koichi Kagesawa, Masahiro Yamashita

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Single-molecules magnets (SMMs) and single-chain magnets (SCMs) are thought to be the magnetic materials for next-generation storage devices since one molecule of an SMM or a chain of an SCM can behave as a "bulk magnet" exhibiting magnetic hysteresis. When designing new SMMs and SCMs, strong magnetic anisotropy must be incorporated so that they undergo slow relaxation of the magnetization, which causes magnetic hysteresis. Moreover, in the case of SCMs, intrachain interactions are necessary. The incorporation of organic radicals satisfies both requirements. Here we discuss examples of SMMs and SCMs containing organic radicals and their magnetic properties.

Original languageEnglish
Title of host publicationMaterials and Energy
PublisherWorld Scientific Publishing Co. Pte Ltd
Pages271-344
Number of pages74
DOIs
Publication statusPublished - 2018 Jan 1

Publication series

NameMaterials and Energy
Volume4
ISSN (Print)2335-6596
ISSN (Electronic)2335-660X

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Renewable Energy, Sustainability and the Environment
  • Materials Science (miscellaneous)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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