Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo; Hiroyuki Isobe; Takatsugu Tanaka; Yasujiro Murata; Michihisa Murata; Koichi Komatsu; Eiichi Nakamura

doi:10.1021/ja056077a

Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H₂@C₆₀, produced a variety of organic and organometallic derivatives of H₂@C₆₀. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H₂@C₆₀Ph₅)C₅H₅, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The ¹H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

Original language	English
Pages (from-to)	17148-17149
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	49
DOIs	https://doi.org/10.1021/ja056077a
Publication status	Published - 2005 Dec 14

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja056077a

Cite this

@article{bc7312eadf314101b319c80dc0e5a2c7,

title = "Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene",

abstract = "Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.",

author = "Yutaka Matsuo and Hiroyuki Isobe and Takatsugu Tanaka and Yasujiro Murata and Michihisa Murata and Koichi Komatsu and Eiichi Nakamura",

year = "2005",

month = dec,

day = "14",

doi = "10.1021/ja056077a",

language = "English",

volume = "127",

pages = "17148--17149",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "49",

}

TY - JOUR

T1 - Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

AU - Matsuo, Yutaka

AU - Isobe, Hiroyuki

AU - Tanaka, Takatsugu

AU - Murata, Yasujiro

AU - Murata, Michihisa

AU - Komatsu, Koichi

AU - Nakamura, Eiichi

PY - 2005/12/14

Y1 - 2005/12/14

N2 - Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

AB - Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

UR - http://www.scopus.com/inward/record.url?scp=29044440821&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=29044440821&partnerID=8YFLogxK

U2 - 10.1021/ja056077a

DO - 10.1021/ja056077a

M3 - Article

C2 - 16332038

AN - SCOPUS:29044440821

VL - 127

SP - 17148

EP - 17149

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 49

ER -

Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this