Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo; Hiroyuki Isobe; Takatsugu Tanaka; Yasujiro Murata; Michihisa Murata; Koichi Komatsu; Eiichi Nakamura

doi:10.1021/ja056077a

Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, Eiichi Nakamura

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H₂@C₆₀, produced a variety of organic and organometallic derivatives of H₂@C₆₀. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H₂@C₆₀Ph₅)C₅H₅, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The ¹H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

Original language	English
Pages (from-to)	17148-17149
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	49
DOIs	https://doi.org/10.1021/ja056077a
Publication status	Published - 2005 Dec 14

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Matsuo, Y., Isobe, H., Tanaka, T., Murata, Y., Murata, M., Komatsu, K., & Nakamura, E. (2005). Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene. Journal of the American Chemical Society, 127(49), 17148-17149. https://doi.org/10.1021/ja056077a

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abstract = "Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.",

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AU - Tanaka, Takatsugu

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AU - Murata, Michihisa

AU - Komatsu, Koichi

AU - Nakamura, Eiichi

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