Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, Eiichi Nakamura

    Research output: Contribution to journalArticle

    50 Citations (Scopus)

    Abstract

    Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

    Original languageEnglish
    Pages (from-to)17148-17149
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume127
    Issue number49
    DOIs
    Publication statusPublished - 2005 Dec 14

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

    Fingerprint Dive into the research topics of 'Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene'. Together they form a unique fingerprint.

  • Cite this

    Matsuo, Y., Isobe, H., Tanaka, T., Murata, Y., Murata, M., Komatsu, K., & Nakamura, E. (2005). Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene. Journal of the American Chemical Society, 127(49), 17148-17149. https://doi.org/10.1021/ja056077a