Optically induced EPR in halogen-bridged linear chain complex [Pt(en)
                        2
                        ][Pt(en)
                        2
                        Cl
                        2
                        ](C10
                        4
                        )
                        4
                        , en=NH
                        2
                        CH
                        2
                        CH
                        2
                        NH
                        2

Noritaka Kuroda; Masamichi Sakai; Masashi Suezawa; Yuichiro Nishina; Koji Sumino; Masahiro Yamashita

doi:10.1080/10587259208028768

Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂

Noritaka Kuroda, Masamichi Sakai, Masashi Suezawa, Yuichiro Nishina, Koji Sumino, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The EPR experiments have been carried out to determine the ligands configurations of the paramagnetic valence anomalies created by UV irradiation in single crystals of [Pt(en) ₂ ][Pt(en) ₂ C1 ₂ ](C10 ₄ ) ₄ , en = ethylenediamine. The hyperfine and superhyperfine spectra show that the UV-induced valence anomalies are diraers of the nearest-neighbor Pt nuclei bearing either electron-like or hole-like spin. A variety of their dynamical properties are extracted from the temperature dependence of the quantum yield.

Original language	English
Pages (from-to)	169-174
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume	216
Issue number	1
DOIs	https://doi.org/10.1080/10587259208028768
Publication status	Published - 1992 Jun 1
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587259208028768

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Kuroda, N., Sakai, M., Suezawa, M., Nishina, Y., Sumino, K., & Yamashita, M. (1992). Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂ Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 216(1), 169-174. https://doi.org/10.1080/10587259208028768

Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂ . / Kuroda, Noritaka; Sakai, Masamichi; Suezawa, Masashi et al.

In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 216, No. 1, 01.06.1992, p. 169-174.

Research output: Contribution to journal › Article › peer-review

Kuroda, N, Sakai, M, Suezawa, M, Nishina, Y, Sumino, K & Yamashita, M 1992, ' Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂ ', Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, vol. 216, no. 1, pp. 169-174. https://doi.org/10.1080/10587259208028768

Kuroda N, Sakai M, Suezawa M, Nishina Y, Sumino K, Yamashita M. Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂ Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 1992 Jun 1;216(1):169-174. doi: 10.1080/10587259208028768

Kuroda, Noritaka ; Sakai, Masamichi ; Suezawa, Masashi et al. / Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂ In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 1992 ; Vol. 216, No. 1. pp. 169-174.

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abstract = " The EPR experiments have been carried out to determine the ligands configurations of the paramagnetic valence anomalies created by UV irradiation in single crystals of [Pt(en) 2 ][Pt(en) 2 C1 2 ](C10 4 ) 4 , en = ethylenediamine. The hyperfine and superhyperfine spectra show that the UV-induced valence anomalies are diraers of the nearest-neighbor Pt nuclei bearing either electron-like or hole-like spin. A variety of their dynamical properties are extracted from the temperature dependence of the quantum yield.",

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Optically induced EPR in halogen-bridged linear chain complex [Pt(en) ₂ ][Pt(en) ₂ Cl ₂ ](C10 ₄ ) ₄ , en=NH ₂ CH ₂ CH ₂ NH ₂

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