Optically induced EPR in halogen-bridged linear chain complex [Pt(en) 2 ][Pt(en) 2 Cl 2 ](C10 4 ) 4 , en=NH 2 CH 2 CH 2 NH 2

Noritaka Kuroda, Masamichi Sakai, Masashi Suezawa, Yuichiro Nishina, Koji Sumino, Masahiro Yamashita

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The EPR experiments have been carried out to determine the ligands configurations of the paramagnetic valence anomalies created by UV irradiation in single crystals of [Pt(en) 2 ][Pt(en) 2 C1 2 ](C10 4 ) 4 , en = ethylenediamine. The hyperfine and superhyperfine spectra show that the UV-induced valence anomalies are diraers of the nearest-neighbor Pt nuclei bearing either electron-like or hole-like spin. A variety of their dynamical properties are extracted from the temperature dependence of the quantum yield.

Original languageEnglish
Pages (from-to)169-174
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume216
Issue number1
DOIs
Publication statusPublished - 1992 Jun 1
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics

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