Optically active phthalocyanines

Nagao Kobayashi

Research output: Contribution to journalReview article

108 Citations (Scopus)

Abstract

Optically active phthalocyanines (Pcs) reported to date have been reviewed. These are classified into three groups: (i) Pcs containing chiral carbons in the side chain. This type of Pc is further divided into two groups, i.e. Pcs with eight long alkyl chains attached directly or indirectly onto the periphery of the Pc core, and Pcs linked with small cyclic compounds. The former always form liquid crystals; (ii) Pcs with optically active aromatic molecules. This group includes helicene and binaphthyl-substituted species; (iii) Pcs with planar asymmetry. Synthesis, characterization and some spectroscopic properties have been summarized, and an outlook for future chiral phthalocyanines given.

Original languageEnglish
Pages (from-to)99-123
Number of pages25
JournalCoordination Chemistry Reviews
Volume219-221
DOIs
Publication statusPublished - 2001 Oct 16

Keywords

  • Chiral
  • Circular dichroism
  • Optically active
  • Phthalocyanine
  • Property
  • Synthesis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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