Abstract
Optically active silica nanoparticles, with a 70-nm diameter, grafted with (P)-1,12-dimethyl-8-methoxycarbonylbenzo[c]phenanthrene-5-carboxyamide were synthesized, and their use in the kinetic resolution of aromatic alcohols was examined. Up to 61% ee for (S)-2,2-dimethyl-1-phenyl-1-propanol was obtained by a preferential precipitation of aggregates formed with (P)-nanoparticles.
Original language | English |
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Pages (from-to) | 3123-3125 |
Number of pages | 3 |
Journal | Organic letters |
Volume | 14 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2012 Jun 15 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry