Open-cage fullerene derivatives with 15-membered-ring orifices

Georgios C. Vougioukalakis, Kosmas Prassides, Josep M. Campanera, Malcolm I. Heggie, Michael Orfanopoulos

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The addition reaction of the N-MEM-ketolactam derivative of [60]fullerene with phenyl, p-Br-phenyl, and p-MeO-phenyl hydrazines proceeds regioselectively, affording three open-cage fullerene derivatives bearing a 15-membered-ring orifice on the fullerene cage. Both experimental data and theoretical calculations were utilized for the structure determination of the new [60]fullerene adducts.

Original languageEnglish
Pages (from-to)4524-4526
Number of pages3
JournalJournal of Organic Chemistry
Volume69
Issue number13
DOIs
Publication statusPublished - 2004 Jun 25

ASJC Scopus subject areas

  • Organic Chemistry

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