TY - JOUR
T1 - One-step heterogeneous assembly of terbium(iii) and silver(i) with thiacalix[4]arene ligands to form a cage including terbium(iii) in an octa-oxygen cube
AU - Tanaka, Teppei
AU - Iki, Nobuhiko
AU - Kajiwara, Takashi
AU - Yamashita, Masahiro
AU - Hoshino, Hitoshi
PY - 2009
Y1 - 2009
N2 - A heterogeneous one-step self-assembly of Ag+, Tb3+, and thiacalix[4]arene (TCAS), of which the donor atoms S and O showed high selectivity toward Ag+ and Tb3+ ions, respectively, afforded a supramolecular cage compound, Ag+ Tb3+, at the center of which an octa-oxygen cube encapsulated the Tb3+ center to completely shield it from solvent molecules.
AB - A heterogeneous one-step self-assembly of Ag+, Tb3+, and thiacalix[4]arene (TCAS), of which the donor atoms S and O showed high selectivity toward Ag+ and Tb3+ ions, respectively, afforded a supramolecular cage compound, Ag+ Tb3+, at the center of which an octa-oxygen cube encapsulated the Tb3+ center to completely shield it from solvent molecules.
KW - Heterometallic complexes
KW - Lanthanides
KW - O,S ligands
KW - Self-assembly
KW - Supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=70349690273&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=70349690273&partnerID=8YFLogxK
U2 - 10.1007/s10847-009-9567-0
DO - 10.1007/s10847-009-9567-0
M3 - Article
AN - SCOPUS:70349690273
VL - 64
SP - 379
EP - 383
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 1388-3127
IS - 3-4
ER -