One-pot aromatic bromination-rearrangement catalyzed by GaCl3

Mieko Arisawa, Atsushi Suwa, Masanori Ashikawa, Masahiko Yamaguchi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Reaction of monoalkylbenzenes with bromine in the presence of a catalytic amount of GaCl3 (5 mol %) initially gives o/p-bromination products, which are converted into mixtures containing considerable amounts of the m-brominated products. Notably, the bromination of dimethyl-, trimethyl-, and tetramethylbenzenes gives dibromo- and/or tribromoarenes, which are converted into monobromoarenes.

Original languageEnglish
Pages (from-to)24-34
Number of pages11
JournalArkivoc
Volume2003
Issue number8
Publication statusPublished - 2003 Dec 1

Keywords

  • Aromatic bromination
  • Gallium trichloride
  • Isomerization

ASJC Scopus subject areas

  • Organic Chemistry

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    Arisawa, M., Suwa, A., Ashikawa, M., & Yamaguchi, M. (2003). One-pot aromatic bromination-rearrangement catalyzed by GaCl3. Arkivoc, 2003(8), 24-34.