One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

Kyosuke Isoda, Hinako Takahashi, Yuichiro Mutoh, Norihisa Hoshino, Tomoyuki Akutagawa

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A crown-ether appended N-heteroacene 1 was reduced in the presence of NaBPh4 to the radical anion 2 by accepting one electron transferred from both the cathode and BPh4- as a reductant. The obtained radical anion 2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.

Original languageEnglish
Pages (from-to)13125-13129
Number of pages5
JournalDalton Transactions
Volume48
Issue number35
DOIs
Publication statusPublished - 2019

ASJC Scopus subject areas

  • Inorganic Chemistry

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