One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

Kyosuke Isoda, Hinako Takahashi, Yuichiro Mutoh, Norihisa Hoshino, Tomoyuki Akutagawa

    Research output: Contribution to journalArticlepeer-review

    1 Citation (Scopus)

    Abstract

    A crown-ether appended N-heteroacene 1 was reduced in the presence of NaBPh4 to the radical anion 2 by accepting one electron transferred from both the cathode and BPh4- as a reductant. The obtained radical anion 2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.

    Original languageEnglish
    Pages (from-to)13125-13129
    Number of pages5
    JournalDalton Transactions
    Volume48
    Issue number35
    DOIs
    Publication statusPublished - 2019

    ASJC Scopus subject areas

    • Inorganic Chemistry

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