One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka; Naohide Matsumoto

doi:10.1246/cl.1997.427

One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H₂O)]ClO₄ and K₂[Hg(CN)₄] {saltmen^2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka, Naohide Matsumoto

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H₂O)]ClO₄ and [Hg(CN)₄]^2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H₂O)}{Hg(CNb)₃}]_n and the other is a discrete trinuclear compound [{Mn(saltmen)(H₂O)}₂{Hg(CN)₄}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.

Original language	English
Pages (from-to)	427-428
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.1997.427
Publication status	Published - 1997 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H₂O)]ClO₄ and K₂[Hg(CN)₄] {saltmen^2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}. / Miyasaka, Hitoshi; Matsumoto, Naohide.

In: Chemistry Letters, No. 5, 01.01.1997, p. 427-428.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H2O)]ClO4 and [Hg(CN)4]2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H2O)}{Hg(CNb)3}]n and the other is a discrete trinuclear compound [{Mn(saltmen)(H2O)}2{Hg(CN)4}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.",

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