One-dimensional chain and discrete trinuclear compounds derived from assembly reaction of [Mn(saltmen)(H2O)]ClO4 and K2[Hg(CN)4] {saltmen2- = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion}

Hitoshi Miyasaka, Naohide Matsumoto

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The reaction of Mn(III) Schiff base complex [Mn(saltmen)(H2O)]ClO4 and [Hg(CN)4]2- gave two distinct compounds with respect to the formula ratio of Mn/Hg and structures, one is a 1-D polymeric compound [{Mn(saltmen)(H2O)}{Hg(CNb)3}]n and the other is a discrete trinuclear compound [{Mn(saltmen)(H2O)}2{Hg(CN)4}]. These compounds were synthesized by making vary the ratio of mixing two building blocks.

Original languageEnglish
Pages (from-to)427-428
Number of pages2
JournalChemistry Letters
Issue number5
DOIs
Publication statusPublished - 1997 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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