Two new 1-D compounds of Rh2(O2CCF3)4 bridged by dicyano linkers were synthesized and struturally characterized. [Rh2(O2CCF3)4 (DM-DCNQI)]∞·(C6H6) (1) and [Rh2(O2CCF3)4 (DCNNQI)]∞·(C7H8) (2) (DM-DCNQI = 2,5-dimethyl-N,N′-dicyanoquinone diiimine, DCNNQI = N,N′-dicyanonaphthaquinone diimine) exhibit different chain motifs because of anti versus syn N - C≡N linkages.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry