One-dimensional assemblies of dirhodium units bridged by N,N′-dicyanoquinonediimine ligands

H. Miyasaka, C. S. Campos-Fernández, J. R. Galán-Mascarós, K. R. Dunbar

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

Two new 1-D compounds of Rh2(O2CCF3)4 bridged by dicyano linkers were synthesized and struturally characterized. [Rh2(O2CCF3)4 (DM-DCNQI)]·(C6H6) (1) and [Rh2(O2CCF3)4 (DCNNQI)]·(C7H8) (2) (DM-DCNQI = 2,5-dimethyl-N,N′-dicyanoquinone diiimine, DCNNQI = N,N′-dicyanonaphthaquinone diimine) exhibit different chain motifs because of anti versus syn N - C≡N linkages.

Original languageEnglish
Pages (from-to)5870-5873
Number of pages4
JournalInorganic chemistry
Volume39
Issue number25
DOIs
Publication statusPublished - 2000 Dec 11
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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