One-dimensional antiferromagnetic chain in [Ni(dmit)22]- salts of [K+ or Rb+(4,13-diaza-18-crown-6)] supramolecular cation

Nobuhiro Takamatsu, Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe, Wataru Fujita, Kunio Awaga

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56 Citations (Scopus)

Abstract

Mixed-stack structures of monovalent [Ni(dmit)2]- and planar M+(4,13-diaza-18-crown-6) (M+ = K+ or Rb+) supramolecular cation were obtained in the isostructural M+(4,13-diaza-18-crown-6)[Ni(dmit)2] salts. The mixed-stack structure decreases the effective π-π overlap of [Ni(dmit)2]- molecules, which results in the one-dimensional Heisenberg antiferromagnetic linear chain of S = 1/2 spins within the crystal.

Original languageEnglish
Pages (from-to)870-871
Number of pages2
JournalInorganic Chemistry
Volume39
Issue number5
DOIs
Publication statusPublished - 2000 Mar 6
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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