On the synthesis conditions of N and N2 endohedral fullerenes

Seitaro Ito, Hidekazu Shimotani, Hidenori Takagi, Nita Dragoe

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The glow discharge at low pressure, under nitrogen atmosphere, is an easy method to synthesize nitrogen encapsulated fullerenes. We present here the results concerning our attempts to optimize the synthesis conditions by this method as well as basic characterization of the obtained products, namely N@C60 and N@C70 together with the molecular counterparts N2@C60 and N2@C70. Changes in pressure, voltage discharge and temperature indicated the optimum yield for N@C60 in our case, which was about 0.0025%, was obtained at 650C, 1 Torr, 850V and 1 to 2mA discharge. In this paper we discuss the HPLC separation of these products and the behavior of N2 in the C60 cage.

Original languageEnglish
Pages (from-to)206-213
Number of pages8
JournalFullerenes Nanotubes and Carbon Nanostructures
Volume16
Issue number3
DOIs
Publication statusPublished - 2008 May 1

Keywords

  • Endohedralfullerene
  • Fullerene
  • Glow discharge
  • Nitrogen
  • Synthesis

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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