Recent observation of the acetal species in the course of auto-amplifying Soai reaction was analysed by the formal kinetic analysis of the experimental data and DFT computations. Kinetic analysis demonstrated convincingly that the observed species cannot be a precursor of the reaction product. Hence, it is an off-loop species that is not important for the process of the chirality amplification. DFT search for a kinetically stable acetal species resulted in the location of a Zn3 cluster stabilized with three ZnOZn bridges.
|Number of pages||8|
|Journal||Bulletin of the Chemical Society of Japan|
|Publication status||Published - 2015 Jan 1|
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