On the origin and structure of the recently observed acetal in the Soai reaction

Ilya Gridnev; Andrey Kh Vorobiev

doi:10.1246/bcsj.20140341

On the origin and structure of the recently observed acetal in the Soai reaction

Ilya Gridnev, Andrey Kh Vorobiev

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Recent observation of the acetal species in the course of auto-amplifying Soai reaction was analysed by the formal kinetic analysis of the experimental data and DFT computations. Kinetic analysis demonstrated convincingly that the observed species cannot be a precursor of the reaction product. Hence, it is an off-loop species that is not important for the process of the chirality amplification. DFT search for a kinetically stable acetal species resulted in the location of a Zn₃ cluster stabilized with three ZnOZn bridges.

Original language	English
Pages (from-to)	333-340
Number of pages	8
Journal	Bulletin of the Chemical Society of Japan
Volume	88
Issue number	2
DOIs	https://doi.org/10.1246/bcsj.20140341
Publication status	Published - 2015 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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On the origin and structure of the recently observed acetal in the Soai reaction

Abstract

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