Observation of X-ray resonant Raman spectra and transition to resonant fluorescence

Yasuo Udagawa, Kazuyuki Tohji

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The first observation of X-ray Raman spectra of transition metal compounds is reported on copper, cuprous oxide, and cupric oxide in resonant, pre-resonant as well as non-resonant conditions. In the non-resonant condition the spectra are, unlike fluorescence X-ray, characteristic of each compound. Upon approaching the resonant condition a smooth and continuous transition from Raman spectra to K fluorescence doublet of copper is observed. The excitation energy dependence of the spectra can be reproduced quite well by a simple calculation employing second-order perturbation theory.

Original languageEnglish
Pages (from-to)101-106
Number of pages6
JournalChemical Physics Letters
Volume148
Issue number2-3
DOIs
Publication statusPublished - 1988 Jul 8
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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