Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction

Katsuhiko Kanaizuka; Sono Sasaki; Takuya Nakabayashi; Hiroyasu Masunaga; Hiroki Ogawa; Takaaki Hikima; Masaki Takata; Masa Aki Haga

doi:10.1021/acs.langmuir.5b02679

Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction

Katsuhiko Kanaizuka, Sono Sasaki, Takuya Nakabayashi, Hiroyasu Masunaga, Hiroki Ogawa, Takaaki Hikima, Masaki Takata, Masa Aki Haga

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidence small-angle and wide-angle X-ray scattering (GISAXS) measurements, and it has been clarified that this film has a crystalline structure. The peaks obtained by GISAXS were changed upon oxidation reaction, which indicates that a change in the orientation of the ruthenium dimer occurred in the film.

Original language	English
Pages (from-to)	10327-10330
Number of pages	4
Journal	Langmuir
Volume	31
Issue number	38
DOIs	https://doi.org/10.1021/acs.langmuir.5b02679
Publication status	Published - 2015 Sep 29
Externally published	Yes

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction. / Kanaizuka, Katsuhiko; Sasaki, Sono; Nakabayashi, Takuya; Masunaga, Hiroyasu; Ogawa, Hiroki; Hikima, Takaaki; Takata, Masaki; Haga, Masa Aki.

In: Langmuir, Vol. 31, No. 38, 29.09.2015, p. 10327-10330.

Research output: Contribution to journal › Article › peer-review

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abstract = "Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidence small-angle and wide-angle X-ray scattering (GISAXS) measurements, and it has been clarified that this film has a crystalline structure. The peaks obtained by GISAXS were changed upon oxidation reaction, which indicates that a change in the orientation of the ruthenium dimer occurred in the film.",

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AU - Kanaizuka, Katsuhiko

AU - Sasaki, Sono

AU - Nakabayashi, Takuya

AU - Masunaga, Hiroyasu

AU - Ogawa, Hiroki

AU - Hikima, Takaaki

AU - Takata, Masaki

AU - Haga, Masa Aki

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Y1 - 2015/9/29

N2 - Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidence small-angle and wide-angle X-ray scattering (GISAXS) measurements, and it has been clarified that this film has a crystalline structure. The peaks obtained by GISAXS were changed upon oxidation reaction, which indicates that a change in the orientation of the ruthenium dimer occurred in the film.

AB - Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidence small-angle and wide-angle X-ray scattering (GISAXS) measurements, and it has been clarified that this film has a crystalline structure. The peaks obtained by GISAXS were changed upon oxidation reaction, which indicates that a change in the orientation of the ruthenium dimer occurred in the film.

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Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction

Abstract

ASJC Scopus subject areas

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