Nucleophilic substitutions on Multipin™ systems linked with a traceless linker

Takashi Takahashi; Satoshi Tomida; Hitoshi Inoue; Takayuki Doi

doi:10.1055/s-1998-1935

Nucleophilic substitutions on Multipin™ systems linked with a traceless linker

Takashi Takahashi, Satoshi Tomida, Hitoshi Inoue, Takayuki Doi

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The displacement of polymer-supported glucose 7 at the 6-position by azide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfonate-linked Multipin™ system giving the corresponding glucose derivatives 8 in excellent yields. Macrocyclization of polymer-supported cyanohydrin ether 13 by displacement of the traceless sulfonate linker provided the cyclic compound 14 in moderate yield but in pure form.

Original language	English
Pages (from-to)	1261-1263
Number of pages	3
Journal	Synlett
Issue number	11
DOIs	https://doi.org/10.1055/s-1998-1935
Publication status	Published - 1998 Nov
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1998-1935

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title = "Nucleophilic substitutions on Multipin{\texttrademark} systems linked with a traceless linker",

abstract = "The displacement of polymer-supported glucose 7 at the 6-position by azide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfonate-linked Multipin{\texttrademark} system giving the corresponding glucose derivatives 8 in excellent yields. Macrocyclization of polymer-supported cyanohydrin ether 13 by displacement of the traceless sulfonate linker provided the cyclic compound 14 in moderate yield but in pure form.",

author = "Takashi Takahashi and Satoshi Tomida and Hitoshi Inoue and Takayuki Doi",

year = "1998",

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AU - Tomida, Satoshi

AU - Inoue, Hitoshi

AU - Doi, Takayuki

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Y1 - 1998/11

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AB - The displacement of polymer-supported glucose 7 at the 6-position by azide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfonate-linked Multipin™ system giving the corresponding glucose derivatives 8 in excellent yields. Macrocyclization of polymer-supported cyanohydrin ether 13 by displacement of the traceless sulfonate linker provided the cyclic compound 14 in moderate yield but in pure form.

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Nucleophilic substitutions on Multipin™ systems linked with a traceless linker

Abstract

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