Nucleophilic substitutions on Multipin™ systems linked with a traceless linker

Takashi Takahashi, Satoshi Tomida, Hitoshi Inoue, Takayuki Doi

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

The displacement of polymer-supported glucose 7 at the 6-position by azide, iodide, and acetate was achieved through a 4-hydroxybenzenesulfonate-linked Multipin™ system giving the corresponding glucose derivatives 8 in excellent yields. Macrocyclization of polymer-supported cyanohydrin ether 13 by displacement of the traceless sulfonate linker provided the cyclic compound 14 in moderate yield but in pure form.

Original languageEnglish
Pages (from-to)1261-1263
Number of pages3
JournalSynlett
Issue number11
DOIs
Publication statusPublished - 1998 Nov
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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