Nucleophilic substitution within the photoionized van der Waals complex C6H5Cl-NH3

Toshihiko Maeyama, Naohiko Mikami

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Efficient generation of C6H5NH3+ was found after the selective ionization of the van der Waals complex C6H5Cl-NH3 which was prepared in a supersonic molecular beam. The action spectrum of the product and its appearance energy were observed by using the two-color mass-selected multiphoton ionization spectroscopy. From the energetics of the reaction it was concluded that the ion-molecule reaction is responsible for the process and the product is generated by the nucleophilic substitution reaction occurring within the photoionized van der Waals complex.

Original languageEnglish
Pages (from-to)6973-6977
Number of pages5
JournalJournal of physical chemistry
Volume94
Issue number18
DOIs
Publication statusPublished - 1990 Jan 1

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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