Abstract
Efficient generation of C6H5NH3+ was found after the selective ionization of the van der Waals complex C6H5Cl-NH3 which was prepared in a supersonic molecular beam. The action spectrum of the product and its appearance energy were observed by using the two-color mass-selected multiphoton ionization spectroscopy. From the energetics of the reaction it was concluded that the ion-molecule reaction is responsible for the process and the product is generated by the nucleophilic substitution reaction occurring within the photoionized van der Waals complex.
| Original language | English |
|---|---|
| Pages (from-to) | 6973-6977 |
| Number of pages | 5 |
| Journal | Journal of physical chemistry |
| Volume | 94 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 1990 Jan 1 |
ASJC Scopus subject areas
- Engineering(all)
- Physical and Theoretical Chemistry
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Maeyama, T., & Mikami, N. (1990). Nucleophilic substitution within the photoionized van der Waals complex C6H5Cl-NH3. Journal of physical chemistry, 94(18), 6973-6977. https://doi.org/10.1021/j100381a012