Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation

Masahiro Ueno; Misato Yonemoto; Masahiro Hashimoto; Andrew E.H. Wheatley; Hiroshi Naka; Yoshinori Kondo

doi:10.1039/b700140a

Nucleophilic aromatic substitution using Et₃SiH/cat. t-Bu-P4 as a system for nucleophile activation

Masahiro Ueno, Misato Yonemoto, Masahiro Hashimoto, Andrew E.H. Wheatley, Hiroshi Naka, Yoshinori Kondo

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

A novel type of deprotonative arylation of nucleophiles was conducted using Et₃SiH/cat. t-Bu-P4 and the powerful S_NAr reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.

Original language	English
Pages (from-to)	2264-2266
Number of pages	3
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/b700140a
Publication status	Published - 2007 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A novel type of deprotonative arylation of nucleophiles was conducted using Et3SiH/cat. t-Bu-P4 and the powerful SNAr reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.",

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AU - Naka, Hiroshi

AU - Kondo, Yoshinori

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