Novel titanium complexes with a reversible structural change on solvent adsorption and desorption

Makoto Kobayashi, Tatsuya Okuhara, Hideki Kato, Sota Sato, Masato Kakihana

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    Two novel pyrazine-2-carboxylate titanium complexes were synthesized from an aqueous solution (1) and 1 in N,Ndimethylformamide (DMF) (2). The structure of 2 was determined to be [Ti6O8(C4H3N2 COO)8(C3H7NO)4]• 4C3H7NO• H2O by single-crystal X-ray analysis. Both complexes exhibited solvent adsorptiondesorption accompanying reversible structural change. 1 and 2 were compatible, and 1 was vital for the synthesis of 2. The degassed 1 showed gate adsorption property for water vapor.

    Original languageEnglish
    Pages (from-to)1050-1052
    Number of pages3
    JournalChemistry Letters
    Volume44
    Issue number8
    DOIs
    Publication statusPublished - 2015 Jan 1

    ASJC Scopus subject areas

    • Chemistry(all)

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