Novel selenium variants of BEDT-TTF

T. Jigami, M. Kawashima, K. Takimiya, Y. Aso, T. Otsubo

Research output: Contribution to journalConference articlepeer-review

5 Citations (Scopus)

Abstract

Bis(ethyleneselenothio)-tetrathiafulvalene (BEST-TTF) and -tetraselenafulvalane (BEST-TSF) have been synthesized using the following two consecutive cyclization methods: (1) one-pot construction of the inner 1,3-dichalcogenole ring from THP-protected 2-(ethynylthio)ethanol and (2) intramolecular transalkylation on a selenium atom toward the formation of the outer dihydrothiaselenin ring. The X-ray crystallographic analysis of BEST-TSF revealed that its molecular and crystal structures are essentially similar to those of BEDT-TTF and related selenium variants.

Original languageEnglish
Pages (from-to)1619-1620
Number of pages2
JournalSynthetic Metals
Volume102
Issue number1-3
DOIs
Publication statusPublished - 1999 Jun
Externally publishedYes
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: 1998 Jul 121998 Jul 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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