Novel Pd(0)-catalyzed cyclization-carbonylation of 2-methyl-1-vinyl-5,6-heptadienyl acetate: The synthesis of (±)-isoiridomyrmecin

Doi Takayuki, Arata Yanagisawa, Keiji Yamamoto, Takashi Takahashi

Research output: Contribution to journalArticle

Abstract

The Pd(0)-catalyzed cyclization-carbonylation of 2-methyl-1-vinyl-5,6-heptadienyl acetate regio-and stereoselectively gave an α-cyclopentylacrylic acid derivative which was applied to the synthesis of (±)-isoiridomyrmecin.

Original languageEnglish
Pages (from-to)1085-1086
Number of pages2
JournalChemistry Letters
Issue number12
Publication statusPublished - 1996 Dec 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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