Novel group 14 elements-bridged self-assembled supramolecules from pyrimidine derivatives and palladium ions

Yoshiyuki Miura, Masato Nanjo, Kunio Mochida, Takeaki Iwamoto, Mitsuo Kira

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A solvent-free complex of dimethyldi(5-pyrimidyl)silane with (ethylenediamine)palladium dinitrate in ratio of 1:3 afforded hitherto unknown three-dimensional, silicon-bridged, self-assembled, cage-like supramolecule via dative: bonding to the transition metal centers. The structure of the supramolecule was fully identified by spectroscopic methods and X-ray diffraction analysis. A germanium analogue was also prepared in the same way.

Original languageEnglish
Pages (from-to)1017-1018
Number of pages2
JournalInorganic Chemistry Communications
Volume7
Issue number9
DOIs
Publication statusPublished - 2004 Sep 1

Keywords

  • Heavier carbon homologues
  • Pyrimidine derivatives
  • Supramolecule
  • X-ray diffraction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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