Nonstoichiometrically activated sintering for Ca1-xSr xTiO3 compound by creating point defects

Ruixing Li, Qing Tang, Shu Yin, Tsugio Sato

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

According to both first principle and materials chemistry, an innovative method for fabricating Ca1-xSrx/TiO3 ceramics was investigated. Ca1-xSrxTiO3 was sintered at temperatures as low as 980 °C by adding 1.0 wt % Li2Si 2O5 without forming a grain boundary phase. It was considered that the sintering was promoted by self-accelerated diffusion due to the formation of point defects caused by doping with Li2Si 2O5. Consequently, a new concept of nonstoichiometrically activated sintering, which is enhanced by point defects without the help of a grain boundary phase, is systematically studied for the first time in the Ca1-xSrxTiO3-Li2Si2O 5 system.

Original languageEnglish
Pages (from-to)273-278
Number of pages6
JournalChemistry of Materials
Volume18
Issue number2
DOIs
Publication statusPublished - 2006 Jan 24

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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