Nonlinear optical properties of novel carborane-ferrocene conjugated dyads. Electron-withdrawing characteristics of carboranes

Norie Tsuboya, Mouad Lamrani, Ryo Hamasaki, Masateru Ito, Masaya Mitsuishi, Tokuji Miyashita, Yoshinori Yamamoto

    Research output: Contribution to journalArticlepeer-review

    103 Citations (Scopus)

    Abstract

    The novel carborane-ferrocene conjugated dyads 1-3 and 6-8 were synthesized and their NLO properties were investigated, ortho-, meta-, and para-carboranes act as electron-withdrawing groups, and the para-carborane dyads 3 and 8 exhibited higher β values (hyperpolarizability) than the ortho- and meta-carborane analogues 1, 2, 6, 7.

    Original languageEnglish
    Pages (from-to)2701-2705
    Number of pages5
    JournalJournal of Materials Chemistry
    Volume12
    Issue number9
    DOIs
    Publication statusPublished - 2002 Jan 1

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Chemistry

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