Nonequilibrium helical-domain morphology in diblock copolymer systems

Takeji Hashimoto, Norihira Mitsumura, Daisuke Yamaguchi, Mikihito Takenaka, Hiroshi Morita, Toshihiro Kawakatsu, Masao Doi

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A new class of domain morphologies in diblock copolymer systems, i.e. a helical domain morphology, was found in a three component mixture of polystyrene-block-polyisoprene diblock copolymer, homo-polystyrene, and homo-polyisoprene. An intuitive explanation of such a domain morphology is given, which predicts that this helical morphology can be observed only in a non-equilibrium state.

Original languageEnglish
Pages (from-to)8477-8481
Number of pages5
JournalPolymer
Volume42
Issue number20
DOIs
Publication statusPublished - 2001 Jan 1
Externally publishedYes

Keywords

  • Helical domain
  • Mixture (blend) of block copolymer and homopolymer
  • Polystyrene-block-polyisoprene

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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