Abstract
A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed.
| Original language | English |
|---|---|
| Article number | C02708SS |
| Pages (from-to) | 2659-2664 |
| Number of pages | 6 |
| Journal | Synthesis |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2008 Aug 18 |
| Externally published | Yes |
Keywords
- Cross-coupling
- Ligands
- Magnesium
- Nickel
- Sulfur
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Kanemura, S., Kondoh, A., Yorimitsu, H., & Oshima, K. (2008). Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand. Synthesis, (16), 2659-2664. [C02708SS]. https://doi.org/10.1055/s-2008-1067193