Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand

Shigenari Kanemura, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed.

Original languageEnglish
Article numberC02708SS
Pages (from-to)2659-2664
Number of pages6
JournalSynthesis
Issue number16
DOIs
Publication statusPublished - 2008 Aug 18
Externally publishedYes

Keywords

  • Cross-coupling
  • Ligands
  • Magnesium
  • Nickel
  • Sulfur

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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