Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand

Shigenari Kanemura; Azusa Kondoh; Hideki Yorimitsu; Koichiro Oshima

doi:10.1055/s-2008-1067193

Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand

Shigenari Kanemura, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed.

Original language	English
Article number	C02708SS
Pages (from-to)	2659-2664
Number of pages	6
Journal	Synthesis
Issue number	16
DOIs	https://doi.org/10.1055/s-2008-1067193
Publication status	Published - 2008 Aug 18
Externally published	Yes

Keywords

Cross-coupling
Ligands
Magnesium
Nickel
Sulfur

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-2008-1067193

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Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand. / Kanemura, Shigenari; Kondoh, Azusa; Yorimitsu, Hideki; Oshima, Koichiro.

In: Synthesis, No. 16, C02708SS, 18.08.2008, p. 2659-2664.

Research output: Contribution to journal › Article › peer-review

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AU - Kanemura, Shigenari

AU - Kondoh, Azusa

AU - Yorimitsu, Hideki

AU - Oshima, Koichiro

PY - 2008/8/18

Y1 - 2008/8/18

N2 - A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed.

AB - A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed.

KW - Cross-coupling

KW - Ligands

KW - Magnesium

KW - Nickel

KW - Sulfur

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Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand

Abstract

Keywords

ASJC Scopus subject areas

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