New stable metallic salt based on a donor molecule containing peri-ditellurium bridges, TMTTeN(SCN)0.88

Emiko Ojima, Bakhyt Zh Narymbetov, Hideki Fujiwara, Hayao Kobayashi, Akiko Kobayashi, Kazuo Takimiya, Tetsuo Otsubo, Fumio Ogura

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7 Citations (Scopus)

Abstract

A new stable organic metal, TMTTeN(SCN)0.88, where TMTTeN is 2,3,6,7-tetramethylnaphtho[1,8-cd:4,5-c′d′]bis[1,2] ditellurole, was obtained. The donors are stacked to form columns and three-dimensional network is developed through Te⋯Te contacts. The salt is highly conductive and keeps metallic behavior down to 4.2 K. Furthermore the salt exhibits Pauli paramagnetic behavior down to 2 K. The extended Hückel tight-binding band calculation was examined.

Original languageEnglish
Pages (from-to)845-846
Number of pages2
JournalChemistry Letters
Issue number8
DOIs
Publication statusPublished - 1999 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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    Ojima, E., Narymbetov, B. Z., Fujiwara, H., Kobayashi, H., Kobayashi, A., Takimiya, K., Otsubo, T., & Ogura, F. (1999). New stable metallic salt based on a donor molecule containing peri-ditellurium bridges, TMTTeN(SCN)0.88. Chemistry Letters, (8), 845-846. https://doi.org/10.1246/cl.1999.845