New sandwich-type phthalocyaninato-metal quintuple-decker complexes

Hailong Wang, Nagao Kobayashi, Jianzhuang Jiang

Research output: Contribution to journalArticlepeer-review

48 Citations (Scopus)

Abstract

Quintuple-decker sandwich: Homoleptic pentakis(2,3,9,10,16,17,23,24- octa(butyloxy)phthalocyaninato) lanthanide-cadmium quintuple-decker complexes were isolated and structurally characterized. They represent the first example of sandwich-type stacked tetrapyrrole-metal complexes with five decks (see figure; the tetrapyrrole molecules are represented by the blue/pink discs, TCB=1,2,4-trichlorobenzene).

Original languageEnglish
Pages (from-to)1047-1049
Number of pages3
JournalChemistry - A European Journal
Volume18
Issue number4
DOIs
Publication statusPublished - 2012 Jan 23

Keywords

  • cadmium
  • lanthanides
  • phthalocyanine
  • sandwich complexes
  • tetrapyrrole

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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