New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4] · CH3CN

Masamichi Umemiya, Makoto Goto, Norihito Kobayashi, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita, Hitoshi Miyasaka, Ken Ichi Sugiura, Harutaka Watanabe, Daichi Suzuki, Hiroshi Ito, Shin Ichi Kuroda

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2 Citations (Scopus)

Abstract

Two charge-transfer salts (DMET)3[Cr(isoq)2(NCS) 4] (1) and (DMET)3[Cr(phen)(NCS)4] · CH3CN (2) have been prepared and characterized. The single-crystal X-ray crystallography revealed that the structures of both salts consist of segregated columns of DMET and metal complex anions. The magnetic and transport properties have shown that these salts are paramagnetic semiconductors.

Original languageEnglish
Pages (from-to)368-369
Number of pages2
JournalChemistry Letters
Volume35
Issue number4
DOIs
Publication statusPublished - 2006 Apr 5

ASJC Scopus subject areas

  • Chemistry(all)

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    Umemiya, M., Goto, M., Kobayashi, N., Takaishi, S., Kajiwara, T., Yamashita, M., Miyasaka, H., Sugiura, K. I., Watanabe, H., Suzuki, D., Ito, H., & Kuroda, S. I. (2006). New charge-transfer salts based on unsymmetrical donor DMET and metal complex anions: (DMET)3[Cr(isoq)2(NCS)4] and (DMET)3[Cr(phen)(NCS)4] · CH3CN. Chemistry Letters, 35(4), 368-369. https://doi.org/10.1246/cl.2006.368