Abstract
Near-infrared magnetic circular dichroism studies of bovine liver catalase and heme octapeptide from equine cytochrome c indicate high-spin character for the former and mixed-spin character for the latter. It is suggested that the ligand-field strength of phenolate is roughly comparable with that of water and hydroxyl anion.
Original language | English |
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Pages (from-to) | 3105-3107 |
Number of pages | 3 |
Journal | Chemical and Pharmaceutical Bulletin |
Volume | 37 |
Issue number | 11 |
DOIs | |
Publication status | Published - 1989 |
Keywords
- catalase
- heme octapeptide
- high-spin
- ligand
- low-spin
- magnetic circular dichroism
- near-infrared
ASJC Scopus subject areas
- Chemistry(all)
- Drug Discovery